نشریه علوم و مهندسی سطح

نشریه علوم و مهندسی سطح

بررسی اثر ترکیب شیمیایی الکترولیت رسوب دهی الکتریکی بر مورفولوژی پوشش‌های نیکل و رفتار الکتروکاتالیستی آنها در الکترواکسایش اتانول رقیق

نوع مقاله : مقاله پژوهشی

نویسندگان
1 دانشکده مواد،دانشگاه صنعتی شیراز، شیراز، ایران
2 دانشکده مواد دانشگاه صنعتی شیراز شیراز ایران
3 شیراز دانشگاه صنعتی شیراز دانشکده شیمی
چکیده
در سال‌های اخیر با پیشرفت فناوری‌های مرتبط با انرژی‌های نوین، طراحی و ساخت جهت بهبود کارامدی الکتروکاتالیست‌ها در پیل سوختی اتانول، مورد توجه قرار گرفته است. در این راستا، افزایش سطح مؤثر الکتروشیمیایی الکتروکاتالیست، بر اساس سنتز مورفولوژی‌های خاص، روش منتخب بسیاری از پژوهش‌ها بوده است. در این پژوهش به روش رسوب دهی الکتریکی دو مرحله‌ای، با تنظیم نسبت‌های مختلف غلظت یون نیکل به افزودنی در ترکیب الکترولیت، پوشش دهی نمونه‌های مختلف نیکل انجام شد و کارامدی آنها جهت الکترواکسایش اتانول در محیط قلیایی بررسی شد. بررسی‌های ساختاری تأیید کرد مورفولوژی نیکل می تواند از ظاهر فلیک‌های عمود بر سطح تا ساختار زبر متخلخل طبقاتی میکرو-نانو مقیاس تغییر کند. با تنظیم نسبت غلظتی یون نیکل به افزودنی معادل 300/238 و 150/119 به ترتیب حداکثر عدد زبری 292/0 و حداقل عدد زبری 144/0میکرومتر گزارش شد. به طوری که نسبت غلظتی 300/238، با ایجاد مورفولوژی متخلخل میکرو-نانو، بیشترین فعالیت الکتروکاتالیستی با خروجی جریان 101 میلی آمپر بر سانتیمتر مربع فراهم شد که ظرفیت بالایی برای الکترواکسایش اتانول غلیظ تا 4 مولار نشان داد. پایداری و دوام این رفتار الکتروکاتالیستی، طی سیکل زنی پتانسیل پیوسته و کرونوآمپرومتری رضایت بخش بود. سهولت تولید و قیمت مناسب این الکتروکاتالیست پایه نیکل، پتانسیل کاربردی شدن در صنعت پیل سوختی اتانول را خواهد داشت.
کلیدواژه‌ها

موضوعات


[1] S. Kumari, Sunaina, S. Devi, M. Jha, Excellent ethanol oxidation and oxygen evolution reaction from ultrafine nickel hydroxide nanorods stabilized at room temperature, Materials Science and Engineering B 306 (2024), 117445. [2] L. Yaqoob, T. Noor and N. Iqbal, A comprehensive and critical review of the recent progress in electrocatalysts for the ethanol oxidation reaction, RSC Adv,11 (2021), 16768–16804. [3] P.E. Sharel, D. Liu, R.A. Lazenby, J. Sloan, M. Vidotti, R. Patrick Unwin, and J.V. Macpherson, Electrodeposition of Nickel Hydroxide Nanoparticles on Carbon Nanotube Electrodes: Correlation of Particle Crystallography with Electrocatalytic Properties, Physical Chemistry C, 120 (2016),16059−16068. [4] N. Boostani a, Sh. Vardak, R. Amini, Z. Mohammadifard, Optimization of Ni-Co-metallic-glass powder (Ni60Cr10Ta10P16B4) (MGP) nanocomposite coatings for direct methanol fuel cell (DMFC) applications, International Journal of Hydrogen Energy, 48 (2023), 10002-10015. [5] S.S. Siwal, S. Thakur, Q.B. Zhang, V.K. Thakur, Electrocatalysts for electrooxidation of direct alcohol fuel cell: chemistry and applications, Materials Today Chemistry 14 (2019) 100182. [6] Z. Zhang,Y. Dong,C. Carlos, and X.Wang, Surface Ligand Modification on Ultrathin Ni(OH)2 Nanosheets Enabling Enhanced Alkaline Ethanol Oxidation Kinetics, ACS Nano, 17 (2023),17180−17189. [7] S.R. Lays, G.M. Iasmim, T.M. Cristiano, E.L-S Franz, I.B.E Katlin, R.S-B Giancarlo, Effect of temperature on the ethanol electrooxidation at Pt Nirich@Ptrich Ni/ C catalyst in acidic and alkaline media, Electroanalytical Chemistry, 857 (2020), 113754. [8] M. Yaldagard, M. Shahbaz, H.W. Kim, and S.S Kim, Ethanol Electro-Oxidation on Catalysts with S-ZrO2-Decorated Graphene as Support in Fuel Cell Applications, Nanomaterials, 12.19 (2022), 3327. [9] M.A.F. Akhairia, S.K.Kamarudin, Erosion-corrosion behavior of highly (DEFC): An overview, International journal of hydrogen energy 41(2016) 4214-4228. [10] Y. Zheng, X. Wan, Xi Cheng, K Cheng, Zh.Dai and Zh. Liu, Advanced Catalytic Materials for Ethanol Oxidation in Direct Ethanol Fuel Cells, Catalysts, 10 (2020), 166. [11] L. An, T.S. Zhao, R. Chen, Q.X. Wu, A novel direct ethanol fuel cell with high power density, Power Sources, 196 (2011), 6219–6222. [12] X. Tan, Sh. Chenb, D. Yanc, R. Dua, Q. Zhonga, L. Liaod, Zhenchen. Tanga and F. Zeng, Recent advances in Ni-based catalysts for the electrochemical oxidation of ethanol, Energy Chemistry, 98(2024), 588-614. [13] Y. Seok Kim, J. Wook Lee, B. Kim, J. Wook Bae, and Ch.H. Chung, Carbon-Neutralized Direct Methanol Fuel Cell Using Bifunctional (Methanol Oxidation/CO2 Reduction) Electrodes, International Journal of Energy Research, 1 (2023) 9277179. [14] J. Bai, D. Liu, J. Yang, and Y. Chen, A Minireview on Nanocatalysts for Electrocatalytic Oxidation of Ethanol, ChemSusChem, 12.10 (2019) 2117-2132. [15] F. Lyu, M. Cao, A. Mahsud and Q. Zhang, Interfacial Engineering of Noble Metals for Electrocatalytic Methanol and Ethanol Oxidation, Materials Chemistry A, 31 (2020)15445-15457. [16] A.N. Vyas, G.D. Saratale, Sh.D. Sartale, Recent developments in nickel-based electrocatalysts for ethanol electrooxidation, International Journal of Hydrogen Energy, 45.10 (2020), 5928-5947. [17] A.B. Soliman, H.S. Abdel-Samad, S.S. Abdel Rehim, M.A. Ahmed, H.H. Hassan, High performance nano-Ni/Graphite electrode for electro-oxidation in direct alkaline ethanol fuel cells, Power Sources, 325 (2016), 653-663. [18] D. Kutyła, K. Nakajima, M. Fukumoto, K. Kołczyk-Siedlecka, M. Wojnicki, Electrocatalytic Performance of Ethanol Oxidation on Ni and Ni/Pd Surface-Decorated Porous Structures Obtained by Molten Salts Deposition/Dissolution of Al-Ni Alloys, International Journal of Molecular Sciences, 24 (2023), 3836. [19] A.F.B. Barbosa, V.L. Oliveira, J. van Drunen and G. Tremiliosi-Filho, Ethanol electro-oxidation reaction using a polycrystalline nickel electrode in alkaline media: Temperature influence and reaction mechanism, Electroanalytical Chemistry, 746 (2015), 31–38. [20] F. Muencha, M. Oezaslanb, M. Raubera, S. Kaserera and Anne Fuchsa, Electroless synthesis of nanostructured nickel and nickeleboron tubes and their performance as unsupported ethanol electrooxidation catalysts, Power Sources, 222 (2013) 243-252. [21] X. Guoa, T. Liangd, D. Zhangb, M. Zhanga, Y. Lina and Ch Lai, Facile fabrication of 3D porous nickel networks for electro-oxidation of methanol and ethanol in alkaline medium, Materials Chemistry and Physics, 221(2019), 390-396. [22] A. Cuña, C. Reyes Plascencia, E. L. da Silva, J. Marcuzzo, S. Khan, N. Tancredi, M. R. Baldan, C. de Fraga Malfatti, Electrochemical and spectroelectrochemical analyses of hydrothermal carbon supported nickel electrocatalyst for ethanol electro-oxidation in alkaline medium,Applied Catalysis B: Environmental, 202 (2017) 95-103. [23] Z. Miao, C. Xu, J. Zhan and Z. Xu‏, Morphology-control and template-free fabrication of bimetallic Cu–Ni alloy rods for ethanol electro-oxidation in alkaline media, Journal of Alloys and Compounds, 855 (2021) 157438. [24] C. Tang, J. Huang, Y. Liu, X. He, G Chen, and Zh He, Ethanol Electrooxidation on an Island-Like Nanoporous Gold/Palladium Electrocatlyst in Alkaline Media: Electrocatalytic Properties and an In Situ Surface-Enhanced Raman Spectroscopy Study, Inorganic Chemistry, 61 (2022) 19388-19398. [25] Ch. Xu, Y. Hu, J Rong, S.P. Jiang, Y. Liu, Ni hollow spheres as catalysts for methanol and ethanol electrooxidation, Electrochemistry Communications, 9 (2007), 2009–2012. [26] A. Hatamie, E. Rezvani, A.S Rasouli, A. Simchi, Electrocatalytic Oxidation of Ethanol on Flexible Three-dimensional Interconnected Nickel/Gold Composite Foams in Alkaline Media, Electroanalysis,31(2019), 504–511. [27] P. Sharma, Radhakrishnan, S.; Khil, M.-S.; Kim, H.-Y.; Kim, B.-S. Simple room temperature synthesis of porous nickel phosphate foams for electrocatalytic ethanol oxidation. J. Electroanal. Chem. 2018, 808, 236–244. [28] Ch. Li, K. Wang, D. Xie, A review of approaches for the design of high-performance electrocatalysts for ethanol electrooxidation, Surfaces and Interfaces, 28 (2022), 101594. [29] Q. Hua, N.M. Alghoraibi, X. Chen, and A.A. Gewirth, Enhanced Methanol Oxidation Using Polymer-Incorporated Rough Pt Electrodes, ACS Catalysis, 13 (2023),10683−10693. [30] A. El Attar, L. Oularbi, S. Chemchoub, and M. El Rhazi, Preparation and characterization of copper oxide particles/polypyrrole (Cu2O/PPy) via electrochemical method: Application in direct ethanol fuel cell, Journal of Hydrogen Energy, 45.15 (2020) 8887-8898. [31] Hashemzadeh M, Raeissi K, Ashrafizadeh F, Khorsand S, Effect of ammonium chloride on microstructure, super-hydrophobicity and corrosion resistance of nickel coatings, Surface and Coatings Technology, 283 (2015), 318–328. [32] R. Zou, S. Xiang, J. Wang, Y. Li, L. Gu and Y. Wang, Dialectical Observation of Controllable Electrodeposited Ni Nanocones: The Unification of Local Disorder and Overall Order, Nanoscale Research Letters, 15 (2020), 91. [33] Leea J.M, Jung K.K, Leeb S.H, Ko J.S, One-step fabrication of nickel nanocones by electrodeposition using CaCl2 ·2H2O as capping reagent, Applied Effect of ammonium chloride on microstructureSurface Science, 369 (2019), 163–169. [34] Gh. Barati Darband, M. Aliofkhazraei, S. Hyun, and S. Shanmugam, Pulse Electrodeposition of a Superhydrophilic and Binder-Free Ni−Fe−P Nanostructure as Highly Active and Durable Electrocatalyst for Both Hydrogen and Oxygen Evolution Reactions, ACS Applied Materials & Interfaces, 12.48 (2020), 53719-53730. [35] P. Salehikahrizsangi, K. Raeissi, F. Karimzadeh, L. Calabrese, E. Proverbio, highly hydrophobic Ni-W electrodeposited film with hierarchical structure, Surface and Coatings Technology, 344 (2018) 626-635. [36] X.R. Ni, Y.T. Zhang, Ch. Wang, Y. Hong, Yuan-Ming Chen, Yuan-Zhang Su, Wei He, Mechanism and Application of Nickel Nano-Cone by Electrodeposition on a Flexible Substrate, Electrochemistry, 28 (2022), 11-29. [37] P. Salehikahrizsangi, K. Raeissi, F. Karimzadeh, L.Calabrese, S. Patane, E. Proverbio, Erosion-corrosion behavior of highly hydrophobic hierarchical Nickel coatings, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 558 (2018), 446-454. [38] M. Dong, P. Chen, T. Hang, M. Li, Nanotwinned copper micro-cone array fabricated by pulse electrodeposition for low-temperature bonding, Materials Letters, 290 (2021). [39] N. Wang, T. Hang, D. Chu, M. Li, Three-Dimensional Hierarchical Nanostructured Cu/Ni–Co Coating Electrode for Hydrogen Evolution Reaction in Alkaline Media, Nano-Micro Lett, 7(2015), 347–352. [40] R. Zou, Y. Zhou, J. Wang, Y. Li, L. Gu, Y. Wang, Electrochemical approach towards the controllable synthesis of nickel nanocones based on the screw dislocation, Applied Nanoscience, 10(2020), 1625-1638. [41] T. Hang, H. Ling, A. Hu, M. Li, Growth Mechanism and Field Emission Properties of Nickel Nanocone Arrays Fabricated by One-Step Electrodeposition, Electrochemical Society, 157 (2010), 624-627. [42] Gh. Barati Darband, M. Aliofkhazraei, A. Dolati b, A. Sabour Rouhaghdam, Electrocrystallization of Ni nanocones from chloride-based bath using crystal modifier by electrochemical methods, Alloys and Compounds, [43]K. Skibinska, M. Huang, G. Mutschke, K. Eckert, G. Włoch, M. Wojnicki, P. Zabinski, On the electrodeposition of conically nano-structured Nickel layers assisted by a capping agent, Electroanalytical Chemistry, 904(2022). [44] Y. Dessie, S. Tadesse, R. Eswaramoorthy, Surface Roughness and Electrochemical Performance Properties of Biosynthesized α-MnO2/NiO-Based Polyaniline Ternary Composites as Efficient Catalysts in Microbial Fuel Cells, Nanomaterial, 2021 (2021). [45] J. Zhang, Zh. Kuang, H Li, Sh. Li, F. X. Xia, Electrode surface roughness greatly enhances the sensitivity of electrochemical non-enzymatic glucose sensors. Electroanalytical Chemistry, 919 (2022). [46] A. Johnson, Electrochemical Surface Area (ECSA) Evaluation in Electrocatalysis: Principles, Measurement Techniques, and Future Perspectives, Engineering in Industrial Research, 6 (2025), 212-222. [47] K. Jiang,Y. Huang, G. Zeng, F.M. Toma, W.A. Goddard, A.T. Bell, Effects of Surface Roughness on the Electrochemical Reduction of CO2 over Cu, ACS Energy Letters, 5 (2020), 1206–1214. [48] Gh.Barati Darband, M. Aliofkhazraei, A. Sabour Rouhaghdam, M.A. Kiani, Three-dimensional Ni-Co alloy hierarchical nanostructure as efficient non-noble-metal electrocatalyst for hydrogen evolution reaction, Applied Surface Science, 465 (2019), 846-862. [49] M.A. Abdel Rahim, R.M. Abdel Hameed, and M.W. Khalil, Nickel as a catalyst for the electro-oxidation of methanol in alkaline medium, Journal of power sources, 134.2 (2004) 160-169. [50] R. Jamil, M. Sohail, N Baig, M.S. Ansari and R. Ahmed, Synthesis of Hollow Pt-Ni Nanoboxes for Highly Efficient Methanol Oxidation, Scientific reports, 9.1 (2019) 15273. [51] F. Wu, Zh. Zhang, F. Zhang, D. Duan, Y. Li, G. Wei, Sh. Liu, Q. Yuan, E. Wang, X. Hao, New Insights into the Electrocatalytic Mechanism of Methanol Oxidation on Amorphous Ni-B-Co Nanoparticles in Alkaline Media, Catalysts, 9.9 (2019) 749. [52] S. Chemchoub, A. El Attar, L. Oularbi, S.A. Younssi, F. Bentiss, Ch. Jama and M. El Rhazi, Electrosynthesis of eco-friendly electrocatalyst based nickel-copper bimetallic nanoparticles supported on poly-phenylenediamine with highest current density and early ethanol oxidation onset potential, International Journal of Hydrogen Energy, 47(92) 39081-39096.