نشریه علوم و مهندسی سطح

نشریه علوم و مهندسی سطح

بررسی واکنش تکامل هیدروژن (HER) پوشش آلیاژی نیکل-مس-آهن به عنوان یک الکتروکاتالیست کارآمد

نوع مقاله : مقاله پژوهشی

نویسندگان
دانشکده مهندسی و علم مواد دانشگاه صنعتی شیراز
چکیده
در این پژوهش پوشش های نیکل خالص، نیکل-مس و نیکل-مس-آهن به عنوان ماده الکتروکاتالیست با استفاده از روش رسوب دهی الکتروشیمیایی برای واکنش تکامل هیدروژن(HER) تولید شد. از میکروسکوپ الکترونی روبشی و پراش پرتو ایکس به ترتیب برای بررسی مورفولوژی و ساختار پوشش های رسوب داده شده استفاده شد. رفتار الکتروکاتالیستی پوشش های تولیدی در محلول یک مولار هیدروکسید پتاسیم توسط آزمون های الکتروشیمیایی ولتامتری سیکلی، ولتامتری خطی روبشی و امپدانس الکتروشیمیایی بررسی شد. نتایج نشان داد مورفولوژی سطح از حالت هرمی و گل کلمی به ترتیب در پوشش های نیکل خالص و نیکل-مس به حالت میکرو/نانومخروط در پوشش نیکل-مس-آهن تغییر کرد. حضور آهن با تغییر ساختار الکترونی و تغییر مورفولوژی سطح پوشش، باعث بهبود رفتار الکتروکاتالیستی گردید. بهترین رفتار الکتروکاتالیستی در پوشش نیکل-مس-آهن بدست آمد که در دانسیته جریان mA/Cm2 10 برای واکنش تولید هیدروژن پتانسیل 195 mV مورد نیاز بود. شیب تافل این پوشش 69.4 mV.dec-1 اندازه گیری شد. همچنین بیشترین سطح فعال الکتروشیمیایی مربوط به این پوشش بود. این پژوهش یک روش کاربردی و موثر را جهت تولید یک ماده الکتروکاتالسیت با رفتار مناسب معرفی می‌کند.
کلیدواژه‌ها

موضوعات


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